彭景翠
理论物理通讯. 1988, 10(4): 387-395.
A three-site model for bridged mixed-valence dimers was further developed in this paper.For the Creutz-Taube ion,the complex is delocalized with strong metal-bridge coupling.For deloca-lized complexes,we introduced a new set of bases (b,n,a) and derived a set of simpler, analytical expressions of three-dimens-onal potential sur-faces Ub,Un and Ua by using the second-orderperturbation theory.The information of the absorption spectrum may be obtained directly from the potential surfaces.