A theory of an electron affinity for an ionic cluster is proposed both in a quasiclassical approach and with quantization of a polarization electric field in a nanoparticle. A critical size of the cluster regarding in formation of an electron's autolocalized state, dependencies of energy and radius of a polaron on a cluster's size are obtained by a variational method. It has been found that binding energy of the electron in the cluster depends on a cluster's radius but a radius of electron's auto-localization does not depend on the cluster's radius and it equals to the polaron radius in a corresponding infinity crystal. A bound state of the electron in a cluster is possible only if the cluster's radius is more than the polaron radius.
Abstract
A theory of an electron affinity for an ionic cluster is proposed both in a quasiclassical approach and with quantization of a polarization electric field in a nanoparticle. A critical size of the cluster regarding in formation of an electron's autolocalized state, dependencies of energy and radius of a polaron on a cluster's size are obtained by a variational method. It has been found that binding energy of the electron in the cluster depends on a cluster's radius but a radius of electron's auto-localization does not depend on the cluster's radius and it equals to the polaron radius in a corresponding infinity crystal. A bound state of the electron in a cluster is possible only if the cluster's radius is more than the polaron radius.
关键词
cluster /
polaron /
autolocalization /
phonon comfinement
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Key words
cluster /
polaron /
autolocalization /
phonon comfinement
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中图分类号：
36.40.Wa
63.20.kd
63.22.Kn
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参考文献
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